Abstract: This paper puts forward the viewpoint that the capstone concepts of operation should develop from Platform-centric warfare and Network-centric warfare to SoS-centric warfare (SCW), analyzes the historical logic, realistic logic and future logic of SCW warfare, expounds the connotation, characteristics and mechanism of SCW warfare, and puts forward the technical architecture and operation mode of SCW warfare based on blockchain of things (BoT). Finally, a preliminary scheme of using edge computing to solve the inherent defects of blockchain architecture is given.